Featured Research paper: Degradation mechanisms and differential curve modeling for non-invasive diagnostics of lithium cells: An overview
De Santis, E., Pennazzi, V., Luzi, M., & Rizzi, A., Renewable and Sustainable Energy Reviews, Volume 211, April 2025
As the world pivots towards sustainable energy solutions, lithium-ion batteries (LIBs) have emerged as indispensable components in electric vehicles (EVs) and renewable energy systems. Their efficiency and longevity, however, are hindered by the phenomenon of battery aging — a multifaceted issue tied to the gradual decline in performance and safety. The recent paper, grounding on a project developed with Ferrari S.p.A., "Degradation mechanisms and differential curve modeling for non-invasive diagnostics of lithium cells: An overview" — published on the prestigious journal Renewable and Sustainable Energy Reviews — offers a detailed exploration of the degradation processes in LIBs, introducing innovative diagnostic methodologies and shedding light on future directions for research and industry.
Our research group at CIPARLABS is strongly committed to the development of technologies for energy sustainability. The topic of lithium-ion battery modeling is among the topics under study and development carried out by our laboratory at the "Sapienza" University of Rome, Department of Information Engineering, Electronics and Telecommunications (DIET).
The Challenge of Battery Aging
Lithium-ion batteries, the backbone of EVs, offer numerous advantages such as high energy density, lightweight construction, and zero emissions. However, they face significant challenges, particularly the progressive degradation of their components. Battery aging manifests as a decline in capacity, efficiency, and safety, influenced by factors such as temperature extremes, charging rates, and the depth of discharge (DOD). Addressing these issues is critical to optimizing battery performance and aligning with broader environmental goals like the UN Sustainable Development Goals (SDGs).
Battery degradation occurs in two primary forms:
Calendar Aging: Degradation during storage, even in the absence of active use, exacerbated by conditions like high temperature and elevated state of charge (SOC).
Cycle Aging: Degradation resulting from repetitive charging and discharging cycles.
These processes lead to two key degradation modes:
Loss of Lithium Inventory (LLI): A reduction in the cyclable lithium ions due to side reactions.
Loss of Active Materials (LAM): Structural damage or dissolution of electrode materials, impacting the battery’s ability to store and deliver energy effectively.
A Diagnostic Revolution: Differential Curve Modeling
The cornerstone of the paper is its focus on differential curve modeling—a non-invasive and powerful tool for diagnosing battery aging. Differential curves, specifically Incremental Capacity (IC) and Differential Voltage (DV) curves, are derived from charge/discharge data. These curves amplify subtle changes in battery behavior, revealing critical insights into degradation mechanisms.
Incremental Capacity (IC) Curves: By plotting the change in charge against voltage, IC curves expose phase transitions in electrode materials, which are sensitive to degradation modes.
Differential Voltage (DV) Curves: These represent voltage changes relative to charge, offering detailed insights into electrode-specific reactions and transitions.
These curves act as diagnostic fingerprints, capturing the nuanced dynamics of battery aging. For instance, shifts in IC curve peaks or DV curve valleys can be linked to specific degradation processes, enabling precise assessments of battery health.
Bridging Science and Application
The paper highlights the practical potential of differential curve analysis. In the automotive sector, this technique can be integrated into Battery Management Systems (BMS) for real-time monitoring and predictive maintenance. By identifying early signs of aging, manufacturers can optimize charging protocols, enhance safety, and extend battery lifespan. This not only reduces costs but also aligns with sustainability objectives by minimizing waste.
In the energy sector, differential curves can support the management of large-scale energy storage systems, ensuring reliability and efficiency. Policymakers, too, can leverage these insights to refine regulations and standards for EVs, accelerating the transition to sustainable transportation.
Future Directions and Innovations
While differential curve modeling offers substantial promise, challenges remain. Noise sensitivity during data processing and variability in experimental conditions necessitate standardized protocols for broader applicability. The integration of machine learning represents an exciting frontier. By training algorithms on IC/DV curve data, researchers can automate diagnostics, identify anomalous patterns, and predict battery failures with unprecedented accuracy.
The non-destructive nature of this approach makes it particularly appealing. Unlike invasive post-mortem analyses, differential curve modeling preserves battery integrity, offering a cost-effective and scalable solution for both academic and industrial applications.
Conclusion
The insights presented in the paper underscore the transformative potential of advanced diagnostic techniques for lithium-ion batteries. By unraveling the complexities of degradation mechanisms and leveraging differential curve modeling, researchers and industry leaders can pave the way for safer, more efficient, and sustainable energy storage solutions. As the global push for electrification and decarbonization accelerates, such innovations are not just timely but essential.
The road ahead is one of collaboration and innovation, bridging gaps between scientific research, industrial practices, and policy frameworks. With tools like differential curve modeling, we are better equipped to meet the challenges of the energy transition and drive a future powered by clean and reliable energy.
Please cite as:
- APA format:
De Santis, E., Pennazzi, V., Luzi, M., & Rizzi, A. (2025). Degradation mechanisms and differential curve modeling for non-invasive diagnostics of lithium cells: An overview. Renewable and Sustainable Energy Reviews, 211, 115349. https://doi.org/10.1016/j.rser.2025.115349
- BibTex format:
@article{ENRICO2025115349,
title = {Degradation mechanisms and differential curve modeling for non-invasive diagnostics of lithium cells: An overview},
journal = {Renewable and Sustainable Energy Reviews},
volume = {211},
pages = {115349},
year = {2025},
issn = {1364-0321},
doi = {https://doi.org/10.1016/j.rser.2025.115349},
url = {https://www.sciencedirect.com/science/article/pii/S136403212500022X},
author = {De Santis Enrico and Pennazzi Vanessa and Luzi Massimiliano and Rizzi Antonello},
keywords = {Ageing, Diagnosis, Degradation mechanisms, Degradation modes, Differential curves, Differential voltage, Lithium-ion batteries, Incremental capacity, State of health}
}